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NEWSFLASH!!!!!!!!!!!!!   The greenhouse effect is not a physical law.  The greenhouse effect is a hypothesis which, by the way was falsified shortly after it was proposed by experimentation by professor Woods.  He showed clearly that the reason a greenouse warms up is due to the glass blocking convection and conduction of heat out of the greenhouse, not any blocking or storing of LW radiation.  He proved this by making a greenhouse from panes of salt, which is invisible to IR and the temperature within the greenhouse reached the same levels as in a greenhouse made of glass.